Glossary of Metallurgical Terms

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C Chemical symbol for Carbon.
Ca Chemical symbol for Calcium.
Calcium In the form of calcium silicide acts as a deoxidizer and degasifier when added to steel. Recent developments have found that carbon and alloy steels modified with small amounts of calcium show improved machinability and longer tool life. Transverse ductility and toughness are also enhanced.
Car Furnace A batch-type furnace using a car on rails to enter and leave the furnace area. Car furnaces are used for lower stress relieving ranges.
Carbon A nonmetallic element that is the principal hardening element present in all steels.  In general, increased carbon content reduces ductility but increases tensile strength and the ability of the steel to harden when cooled rapidly from elevated temperatures.   At temperatures below 700°C, carbon is present in steel as iron carbide, cementite, Fe3C.  The cementite forms lamellae, which “reinforces” the iron.  This explains why a steel with a high-carbon content is harder than one with a low-carbon content.  Generally, 0.05 to 0.25% is considered low-carbon steel, 0.25 to 0.5% is medium-carbon and 0.5 to 0.9% is high-carbon. The mixture of ferrite and cementite in a grain is called pearlite.  Ductility and weldability decrease with increasing carbon content.  Austenite can dissolve up to 2% carbon. When cooled in water or oil, carbon stays in a supersaturated solution of martensite.
Carbon Potential A measure of the ability of an environment containing active carbon to alter or maintain, under prescribed conditions, the carbon level of the steel. NOTE: In any particular environment, the carbon level attained will depend on such factors as temperature, time and steel composition.
Carbon Restoration Replacing the carbon lost in the surface layer from previous processing by carburizing this layer to substantially the original carbon level. Sometimes called recarburizing.
Carbon Steel A steel whose properties are determined primarily by the amount of carbon present. Apart from iron and carbon, manganese up to 1.5% may be present as well as residual amounts of alloying elements such as nickel, chromium, molybdenum, etc. It is when one or more alloying elements are added in sufficient amount that it is classed as an alloy steel. Also known as ordinary steel, straight carbon steel, or plain carbon steel.
Carbo-Nitriding A case-hardening process in which steel components are heated in an atmosphere containing both carbon and nitrogen.
Carburizing The introduction of carbon into the surface layer of a steel that has a low carbon content. The process is carried out by heating the components in a solid liquid, or gaseous carbon containing medium. The depth of penetration of carbon into the surface is controlled by the time and temperature of the treatment. After carburising it is necessary to harden the components by heating to a suitable temperature and quenching.
Case The surface layer of a steel whose composition has been changed by the addition of carbon, nitrogen, chromium, or other material at high temperature.
Case-Hardening The process of hardening the surface of steel whilst leaving the interior unchanged. Both carbon and alloy steels are suitable for case-hardening providing their carbon content is low, usually up to a maximum of 0.2%. Components subject to this process, particularly in the case of alloy steels, have a hard, wear-resistant surface with a tough core.
Cast Iron A definition can be applied that Cast Iron is an alloy of iron and carbon in which the carbon is in excess of the amount that can be retained in solid solution in austenite at the eutectic temperature. Carbon is usually present in the range of 1.8% to 4.5%, in addition, silicon, manganese, sulfur and phosphorus are contained in varying amounts. Various types of cast iron are covered by a British Standard classification and includes grey, malleable and white irons. Elements such as nickel, chromium, molybdenum, vanadium can be added to produce alloy cast irons.
Cast Steel A term originally applied to crucible steel and sometimes today used to describe tool steels. The term is misleading and is falling into misuse. It can also be applied to steel castings made by pouring molten steel into a mould but which are not subject to further forging or rolling.
Cb Chemical symbol for Columbium.
Ce Chemical symbol for Cerium.
Cementite An iron carbide (Fe3C) constituent of steel. It is hard, brittle and crystalline. Steel which has cooled slowly from a high temperature contains ferrite and pearlite in relative proportions varying with the chemical composition of the steel. Pearlite is a lamellar structure of ferrite and cementite.
Charpy Test A test to measure the impact properties of steel. A prepared test piece, usually notched, is broken by a swinging pendulum. The energy consumed in breaking the test piece is measured in Joules. The more brittle the steel the lower the impact strength. Izod is a similar and more widely used impact test in this country. Both are quoted in the current edition of BS 970.
Chromium When used as an alloying element, chromium increases the hardenability of steel and in association with high carbon gives resistance to wear and abrasion. Chromium has an important effect on corrosion resistance and is present in stainless steels in amounts of 12% to 20%. It is also used in heat-resisting steels and high duty cast irons.
Co Chemical symbol for Cobalt.
Cobalt An alloying element used in tool, magnet and heat resisting steels. Together with tungsten and molybdenum, cobalt is used to form the super high speed steels. It improves the red hardness value of the steel, that is, it enables the steel to resist softening at a high temperature or in the case of a cutting tool to hold its edge under severe conditions.
Coefficient of Expansion The ratio of change in length, area, or volume per degree to the corresponding value at a standard temperature.
Cogging An intermediate rolling process when a hot ingot is reduced to a bloom or slab in a cogging mill.
Cold Drawing The process of reducing the cross sectional area of wire, bar or tube by drawing the material through a die without any pre-heating. Cold drawing is used for the production of bright steel bar in round square, hexagonal and flat section. The process changes the mechanical properties of the steel and the finished product is accurate to size, free from scale with a bright surface finish.
Cold Treatment Exposing to suitable subzero temperatures for the purpose of obtaining desired conditions or properties such as dimensional or microstructural stability. When the treatment involves the transformation of retained austenite, it is usually followed by tempering.
Cold Working Altering the shape or size of a metal by plastic deformation. Processes include rolling, drawing, pressing, spinning, extruding and heading, it is carried out below the recrystallisation point usually at room temperature. Hardness and tensile strength are increased with the degree of cold work whilst ductility and impact values are lowered. The cold rolling and cold drawing of steel significantly improves surface finish.
Compressive Strength The maximum compressive stress that a material is capable of developing, based on original area of cross section. If a material fails in compression by a shattering fracture, the compressive strength has a very definite value. If a material does not fail in compression by shattering fracture, the value obtained for compressive strength is an arbitrary value depending upon the degree of distortion that is regarded as indicating complete failure of the material.
Contact Corrosion When two dissimilar metals are in contact without a protective barrier between them and they are in the presence of liquid, an electrolytic cell is created. The degree of corrosion is dependent on the area in contact and the electro-potential voltage of the metals concerned. The less noble of the metals is liable to be attacked, i.e. zinc will act as a protector of steel in sea water whereas copper or brass will attack the steel in the same environment.
Contact Fatigue Cracking and subsequent pitting of a surface subjected to alternating Hertzian stresses such as those produced under rolling contact or combined rolling and sliding. The phenomenon of contact fatigue is encountered most often in rolling-element bearings or in gears, where the surface stresses are high due to the concentrated loads and are repeated many times during normal operation.
Continuous Casting A method of producing blooms, billets and slabs in long lengths using water cooled moulds. The castings are continuously withdrawn through the bottom of the caster whilst the teeming of the metal is proceeding. The need for primary and intermediate mills and the storage and use of large numbers of ingot moulds is eliminated. The continuous casting process is also used in the production of cast iron, aluminium and copper alloys.
Continuous Type Furnace A furnace used for heat-treating materials that progress continuously throughout the furnace, entering one door and being discharged from another.
Control Zone A portion of the working zone of a piece of thermal processing equipment having a separate sensor/instrument/heat input or output mechanism to control its temperature.
Controlled Atmosphere A gas or mixture of gases in which steel is heated to produce or maintain a specific surface condition. Controlled atmosphere furnaces are widely used in the heat treatment of steel as scaling and decarburisation of components is minimized by this process.
Controlled Cooling Cooling from an elevated temperature in a pre-determined manner, to avoid hardening, cracking, or internal damage, or to produce desired microstructure or mechanical properties.
Cooling Curve A curve showing the relation between time and temperature during the cooling of a material.
Cooling Stresses Residual stresses resulting from non-uniform distribution of temperature during cooling.
Core In the case of steel this refers to a component that has been case-hardened where the centre is softer than the hard surface layer or case. It can also be applied to the central part of a rolled rimming steel.
Correction Factor That number of degrees, determined from the most recent calibration, which must be added to, or subtracted from, the temperature reading of a sensor, or an instrument, or a combination thereof (system) to obtain NIST true temperature. When expressed as a percent, it means percent of reading. The correction factors of sensors and instruments are usually kept separately and added together algebraically when a combination is used.
Corrosion Embrittlement The severe loss of ductility of a metal resulting from corrosive attack, usually intergranular and often not visually apparent.
Corrosion Fatigue Fatigue that arises when alternating or repeated stress combines with corrosion. The severity of the action depends on the range and frequency of the stress, the nature of the corroding condition and the time under stress.
Cr Chemical symbol for Chromium.
Creep The dimensional change with time of a material under a mechanical load.  The flow or plastic deformation of metals held for long periods of time at stresses lower than the normal yield strength.  Plastic deformation that proceeds slowly and continuously when stress is applied at elevated temperatures.  In steel, creep is negligible below about 300°C (572°F).  Methods of creep testing involve the determination of strain/time curves under constant tensile load and at constant temperature.
Creep Strength

The constant nominal stress that will cause a specified quantity of creep or secondary creep in a given time at a constant temperature. The resulting rate of continuous deformation is often expressed as PSI to produce 0.1 percent elongation in 10,000 hours at the temperature indicated.

Critical Cooling Rate The slowest rate of cooling required to suppress phase changes.  The term is most usually applied to the rate of quenching various products that are heated or “worked.”  For example, the rate required to produce a martensic structure in the hardening of steel.  The critical cooling rate in patenting is selected to provide minimum pearlitic spacing.
Critical Diameter  (D) Diameter of the bar that can be fully hardened with 50% martensite at its center.
Critical Point This generally refers to a temperature at which some chemical or physical change takes place. These transformations cause evolution of heat on cooling or absorption of heat on heating and appear as discontinuities or arrest points in the heating and cooling curves. The temperatures vary with the carbon content of the steel and the rate of cooling.
Critical Range The temperature range between an upper and lower critical point for a given material.
Critical Temperature The temperature at which some phase change occurs in a metal during heating or cooling, i.e. the temperature at which an arrest or critical point is shown on heating or cooling curves.
Crystalline Fracture A type of fracture that appears bright and glittering, it having formed along the cleavage planes of the individual crystals. Normally an indication that brittle fracture has occurred.
Crystallization  (1) The separation, usually from a liquid phase on cooling, of a solid crystalline phase. (2) Sometimes erroneously used to explain fracturing that actually has occurred by fatigue.
Cu Chemical symbol for Copper.
Cyanide Hardening A process of introducing carbon and nitrogen into the surface of steel by heating it to a suitable temperature in a molten bath of sodium cyanide, or a mixture of sodium and potassium cyanide, diluted with sodium carbonate and quenching in oil or water. This process is used where a thin case and high hardness are required.
Cycle Annealing An annealing process employing a predetermined and closely controlled time-temperature cycle to produce specific properties or microstructures.
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